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K1+XV2O4+X – Sr2V2O5 – SrV2O4

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The phase composition of a Ê2O – SrO – V2O5 – V2O3 system fragment at 9000Ñ in sealed evacuated quartz ampoules with a residual air pressure of 0.001 mm was investigated. 0.001 mm Hg. Based on the X-ray phase analysis of sintering products, it was concluded that there are three new phases: KSr5V6O15, K3+xSr3-xV6O15, K1+xSrV6x+4O12x+8 (0 ≤ x ≤ 1). The last two phases at temperatures below ~ 77 K are attracted by a magnet. Built phase diagram. The radiographic characteristics of the new compounds are given.

Keywords: vanadite potassium - strontium., K1 + xSrV6x + 4O12x + 8, K3 + xSr3-xV6O15, KSr5V6O15, KSrV4O8, KSrV2O5, K2O - SrO - V2O5 - V2O3 system


Reference

K1+XV2O4+X – Sr2V2O5 – SrV2O4 // Íîîñôåðà. Îáùåñòâî. ×åëîâåê. – 2019. – ¹ 3;
URL: www.es.rae.ru/noocivil/260-1941 (Date Access: 21.12.2024).


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